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<meta content="Canty, A.J." name="eprints.creators_name" />
<meta content="Hettinga, M.J.G." name="eprints.creators_name" />
<meta content="Patel, J." name="eprints.creators_name" />
<meta content="Pfeffer, M." name="eprints.creators_name" />
<meta content="Skelton, B.W." name="eprints.creators_name" />
<meta content="White, A.H." name="eprints.creators_name" />
<meta content="allan.canty@utas.edu.au" name="eprints.creators_id" />
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<meta content="2008-01-03 23:05:37" name="eprints.datestamp" />
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<meta content="Neopentyl- and trimethylsilylmethylpalladium chemistry:
synthesis of reagents for organopalladium chemistry and the
crystal structure of the neopentyl(phenyl)palladium(IV) complex [Pd(mq)(CH2CMe3)Ph(bpy)]Br (mq = 8-methylquinolinyl, bpy = 2,2'-bipyridine)" name="eprints.title" />
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<meta content="259901" name="eprints.subjects" />
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<meta content="Organopalladium; Intramolecular coordination; Neopentyl; Trimethylsilylmethyl; Palladium(IV); 8-Methylquinolinyl
" name="eprints.keywords" />
<meta content="The definitive version is available at http://www.sciencedirect.com
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<meta content="Synthetic routes to neopentyl and trimethylsilylmethyl complexes of Pd(II) are reported, Pd(CH2EMe3)Ph(tmeda) [E = C (1), Si (3); tmeda = N,N,N',N'-tetramethylethylenediamine] and Pd(CH2EMe3)Ph(bpy) [E = C (2), Si (4); bpy = 2,2'-bipyridine]. Complexes 1 and 3 are formed on the reaction of PdIPh(tmeda) with LiCH2EMe3, and they react with bpy to give 2 and 4. Oxidative addition reactions of 8-(bromomethyl)quinoline (mqBr) with Pd(CH2EMe3)Ph(bpy) result in the formation of octahedral
Pd(IV) complexes [Pd(mq)(CH2EMe3)Ph(bpy)]Br [E = C (5), Si (6)]. An X-ray structural analysis for 5, the first example of a stable cationic arylpalladium(IV) complex, shows a fac-PdC3N3 configuration with the neopentyl group trans to the quinoline nitrogen donor atom." name="eprints.abstract" />
<meta content="2002" name="eprints.date" />
<meta content="published" name="eprints.date_type" />
<meta content="Inorganica Chimica Acta" name="eprints.publication" />
<meta content="338" name="eprints.volume" />
<meta content="94-98" name="eprints.pagerange" />
<meta content="10.1016/S0020-1693(02)00978-7" name="eprints.id_number" />
<meta content="TRUE" name="eprints.refereed" />
<meta content="0020-1693" name="eprints.issn" />
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7 (1988) 1363." name="eprints.referencetext" />
<meta content="Canty, A.J. and Hettinga, M.J.G. and Patel, J. and Pfeffer, M. and Skelton, B.W. and White, A.H. (2002) Neopentyl- and trimethylsilylmethylpalladium chemistry: synthesis of reagents for organopalladium chemistry and the crystal structure of the neopentyl(phenyl)palladium(IV) complex [Pd(mq)(CH2CMe3)Ph(bpy)]Br (mq = 8-methylquinolinyl, bpy = 2,2'-bipyridine). Inorganica Chimica Acta, 338 . pp. 94-98. ISSN 0020-1693" name="eprints.citation" />
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synthesis of reagents for organopalladium chemistry and the
crystal structure of the neopentyl(phenyl)palladium(IV) complex [Pd(mq)(CH2CMe3)Ph(bpy)]Br (mq = 8-methylquinolinyl, bpy = 2,2'-bipyridine)" name="DC.title" />
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<meta content="Synthetic routes to neopentyl and trimethylsilylmethyl complexes of Pd(II) are reported, Pd(CH2EMe3)Ph(tmeda) [E = C (1), Si (3); tmeda = N,N,N',N'-tetramethylethylenediamine] and Pd(CH2EMe3)Ph(bpy) [E = C (2), Si (4); bpy = 2,2'-bipyridine]. Complexes 1 and 3 are formed on the reaction of PdIPh(tmeda) with LiCH2EMe3, and they react with bpy to give 2 and 4. Oxidative addition reactions of 8-(bromomethyl)quinoline (mqBr) with Pd(CH2EMe3)Ph(bpy) result in the formation of octahedral
Pd(IV) complexes [Pd(mq)(CH2EMe3)Ph(bpy)]Br [E = C (5), Si (6)]. An X-ray structural analysis for 5, the first example of a stable cationic arylpalladium(IV) complex, shows a fac-PdC3N3 configuration with the neopentyl group trans to the quinoline nitrogen donor atom." name="DC.description" />
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<h1 class="ep_tm_pagetitle">Neopentyl- and trimethylsilylmethylpalladium chemistry: synthesis of reagents for organopalladium chemistry and the crystal structure of the neopentyl(phenyl)palladium(IV) complex [Pd(mq)(CH2CMe3)Ph(bpy)]Br (mq = 8-methylquinolinyl, bpy = 2,2'-bipyridine)</h1>
<p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Hettinga, M.J.G.</span> and <span class="person_name">Patel, J.</span> and <span class="person_name">Pfeffer, M.</span> and <span class="person_name">Skelton, B.W.</span> and <span class="person_name">White, A.H.</span> (2002) <xhtml:em>Neopentyl- and trimethylsilylmethylpalladium chemistry: synthesis of reagents for organopalladium chemistry and the crystal structure of the neopentyl(phenyl)palladium(IV) complex [Pd(mq)(CH2CMe3)Ph(bpy)]Br (mq = 8-methylquinolinyl, bpy = 2,2'-bipyridine).</xhtml:em> Inorganica Chimica Acta, 338 . pp. 94-98. ISSN 0020-1693</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2794/1/ICA338_2C_94.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2794/1/ICA338_2C_94.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />144Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="3824" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/S0020-1693(02)00978-7">http://dx.doi.org/10.1016/S0020-1693(02)00978-7</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Synthetic routes to neopentyl and trimethylsilylmethyl complexes of Pd(II) are reported, Pd(CH2EMe3)Ph(tmeda) [E = C (1), Si (3); tmeda = N,N,N',N'-tetramethylethylenediamine] and Pd(CH2EMe3)Ph(bpy) [E = C (2), Si (4); bpy = 2,2'-bipyridine]. Complexes 1 and 3 are formed on the reaction of PdIPh(tmeda) with LiCH2EMe3, and they react with bpy to give 2 and 4. Oxidative addition reactions of 8-(bromomethyl)quinoline (mqBr) with Pd(CH2EMe3)Ph(bpy) result in the formation of octahedral
Pd(IV) complexes [Pd(mq)(CH2EMe3)Ph(bpy)]Br [E = C (5), Si (6)]. An X-ray structural analysis for 5, the first example of a stable cationic arylpalladium(IV) complex, shows a fac-PdC3N3 configuration with the neopentyl group trans to the quinoline nitrogen donor atom.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com
</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">Organopalladium; Intramolecular coordination; Neopentyl; Trimethylsilylmethyl; Palladium(IV); 8-Methylquinolinyl
</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2794</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">04 Jan 2008 10:05</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2794;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2794">item control page</a></p>
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